Please see our new publication in Atmospheric Chemistry and Physics on the role of desorption lifetimes and activities on multiphase chemical kinetics. We also provide a parametrization to estimate desorption energies for implementation in multiphase chemical kinetics models:

Knopf, D. A., Ammann, M., Berkemeier, T., Pöschl, U., and Shiraiwa, M.: Desorption lifetimes and activation energies influencing gas–surface interactions and multiphase chemical kinetics, Atmos. Chem. Phys., 24, 3445–3528, 2024.

This article is available here.